next up previous
Next: a) Up: No Title Previous: d)

(15 pts) Predicting Bulk Moduli/Compressibility of Metals

In this problem you will use your knowledge of quantum mechanics to predict a measurable quantity which effects your daily life, the resistance of metals to being compressed. The quantity which measures this ``resistance'' is the bulk modulus . The higher B is, the more difficult (greater energy cost) it is to compress (decrease the volume of) the metal.

At the end of the problem, you will have the opportunity to compare your own quantum calculations with actual experimental results.

To perform this calculation, you will need to accept as given but one fact which we have not discussed yet in lecture. This one fact is the Pauli Exclusion Principle, which you learned about in elementary chemistry class. The principle states that in systems containing more than one electron, at most two (2) electrons (one spin-up and the other spin-down) may occupy the same quantum energy state at once.

You will make the simplifying assumption that the bulk modulus of a metal at room temperature is close enough to its modulus at zero temperature (T=0) so that for the purposes of this problem, you can assume that the electrons in a metal are all in their lowest energy configuration.

The notation used in this problem is as follows. You will consider a cubic chunk of metal of side L and volume and containing N electrons of mass m. We will call the volume density of electrons . The energies of individual electrons will be denoted by the lower case Greek 's; the energy of the entire collection of electrons, the metal as a whole will be denoted with an upper case Roman E. The symbols and refer to the counting of states, just as they did in our black body discussions, and the symbols and refer to the counting of electrons. From the Pauli principle then , . As the electrons seek the lowest possible energy configuration, they fill all available energy states up to some maximum energy level which we will call ``'' for historical reasons. is known as the the Fermi energy. (For those taking 8.044: the Fermi energy is just the chemical potential the energy cost of adding a single particle to the system.)





next up previous
Next: a) Up: No Title Previous: d)



Prof. Tomas Alberto Arias
Thu Oct 12 17:30:59 EDT 1995