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Impossibily of electrons absorbing photons in free space

Finally note that when the wavelength of the incoming light exceeds , there is always an outgoing photon carrying a finite amount of energy . It is impossible for an electron in free space to completely absorb the energy and momentum of a photon and still satisfy the basic laws of the conservation of energy and momentum. You will recall, however, that this complete absorption is precisely what we assumed happened in our analysis of the photoelectric effect. The resolution of this ``paradox'' is just to observe that the electrons in the photoelectric effect are not free but are inside of a crystal which can help absorb the momentum of the incoming photons.



Prof. Tomas Alberto Arias
Wed Oct 11 20:18:35 EDT 1995