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Probability Currents

We will now use a very general procedure to show that probability is conserved under the dynamics given by the TDSE. By conservation of probability we mean the requirement that the integral of will remain properly normalized for all time t>0. The procedure we are about to use is very general. It is used, for instance, to show that energy and momentum are conserved in electrodynamics under Maxwell's equations and that mass and momentum are conserved under the equations of Newtonian fluid flow.

As we saw in the previous section the mathematical condition that be conserved is that it obey the continuity equation with no source term ( as evolves according to the TDSE. To demonstrate conservation all that we must now do is identify a probability current density so that .

To identify this current density, we begin with the time derivative in the equation of continuity (3) and then employ our knowledge of the time derivatives of through the TDSE (2),

To complete the identification of , express the hand side of the above expression as the divergence of some quantity. This we do by noting the following identity of vector calculus, which amounts to integration by parts,

Inserting this into our previous result gives

 

Thus, our final form for the probability current density is

 

For developing under the Schrödinger equation, this satisfies the continuity equation with no source term,

Thus, probability is conserved and the rate of change of probability in a region V balances the total flux leaving the region,

and the total probability in all of space is conserved,



Prof. Tomas Alberto Arias
Thu Oct 12 12:30:23 EDT 1995