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Eigenenergies

To find the allowed energies, we must impose the condition on (6) that show no exponentially growing behavior. To explore the exponential behaviors of the solution in region III, we expand the hyperbolic functions in in their exponential components,

The first term gives rise to exponential growth as and so its prefactor must be zero,

 

To simplify this condition, we expand the double angle trigonometric functions and multiplying through by . (Note that this may introduce an extraneous root at k=0) The eigensolution condition on k and then becomes

 

Having succeeded in factoring our expression in the last step, we have simplified the condition considerably. Unfortunately, the factors still represent fairly complex transcendental equations for the energy E. To proceed, we must resort to a numerical or graphical solution method for each of the two roots of (17).

  

We will see later that these roots represent either the odd or even solutions, respectively.

The graphical solution proceeds as follows. First we note that k is related to E through (11)

so that working with either k or E is nearly equivalent. Next, and k share the relationship,

 

where we have defined

Plotting the three functions , and on the same graph, the solutions to (18) and (19) may be read off as the k values of the intersections of the curves in Figure 1.7.

 

The first intersection (at k=0) is an extraneous root we introduced when we multiplied by . This must extraneous root, because when we let in (16), which is the value of the prefactor to the exponentially growing solution in region III, we get , which would lead to exponentially growing solutions. The only extraneous root we introduced was for k=0, all remaining intersections of the curves in the figure then represent allowable eigensolultions to the TISE.

From the figure we learn several things. First, we see that there is always at least one allowed energy, corresponding to the intersection of the curve with the first branch of the curve. This occurs for and is always the first, lowest energy (ground state) solution. After that, heads toward at , and there may or may not be further solutions according to whether , which would then allow an intersection with the next branch.

For the case in the figure and so there are three allowed pure energy states, one at , and one at . We see that in general there are allowed eigenenergies, where is the notation for taking the integer part of a real number x.

For the lower bound states, the curve stays relatively close to the k-axis so that the solutions are at approximately for , correspondingly precisely to the Bohr-Sommerfeld solutions

for a particle in a box of size 2a and matching, as we shall discuss shortly, the eigenenergies for the infinite square well, . This is physically reasonable, if the solutions have energies E far below , these states act as through were infinite.

Finally, note that as E (or equivalently k) increases the curve intersects alternately the two curves and so that the root corresponds to even numbered excited solutions (we regard the ground state as n=0) root corresponds to the odd numbered solutions.



next up previous
Next: Wavefunctions Up: Finite Square Well Previous: Discussion of solution



Prof. Tomas Alberto Arias
Thu Oct 12 21:20:39 EDT 1995