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(7 pts) The Uncertainty Principle: The energy of confinement

To make color displays with semiconductor devices, workers try to increase the energy of electrons several volts by confining the electrons in very small crystals.

The behavior of an electron moving through a crystal is much like that of an electron moving through free space, except that because of the interaction between the electron and the crystal the electron acts as though it had a different mass, an ``effective mass''. In Germanium, for instance, this mass is where is the mass of an electron in free space.

Check the feasibility of this approach in Germanium by using the uncertainty principle to estimate the kinetic energy of an electron of mass confined to a cube of side L. How does the energy of the electron vary as L decreases? What size L is needed to increase the energy of the electron by 1 eV? Is this reasonable or is it smaller than the average spacing between atoms in Germanium? (The density of Germanium is 5.32 and its atomic weight is 72.6 .)



Prof. Tomas Alberto Arias
Thu Oct 12 16:58:54 EDT 1995