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Region I

In this region, is a constant. To remind ourselves that this constant is positive, we shall rewrite (2) as

 

where is a real constant defined by

 

By convention we always choose itself to be positive. (3) is a second order linear differential equation with constant coefficients. Such linear, constant coefficient differential equations always possesses solutions of the form for some constants and A. The above equation is satisfied so long as . There are thus have two linearly independent solutions and . Because the TISE is linear, we may add these two solutions to produce a more general solution . Finally, because (3 is a second order equation, there are at most two linearly independent solutions and thus we have found the most general solution to the TISE in region I:

 

The behavior of any physical state in region I must be of the form (5). However, the converse of this statement is not true. Just because a function obeys the TISE in region I does not mean that it is a physically acceptable solution. For instance, if in 5, then would grow exponentially as , meaning that as we go further and further to the left of the well, the probability of finding the particle becomes greater and greater. for all meaning that there is an infinite weight of finding the particle at a infinite distance from the well. Physically, we see that if , cannot represent the state of the particle in the system we are studying. Mathematically, we must reject this solution because the probability cannot be normalized. These considerations lead us to the first restriction which we place on allowable wavefunctions on physical grounds,

 

We thus insist that for any physically acceptable solution, . To reduce the complexity of the algebra, we define so that our final form for the behavior of the wavefunction in region I is

 

One may arrive at (7) directly by observing that it is the only solution which obeys the TISE for region I (3) and is consistent with the boundary condition (6).



next up previous
Next: Boundary Between Region Up: Finite Square Well Previous: Finite Square Well



Prof. Tomas Alberto Arias
Thu Oct 12 21:20:39 EDT 1995