The time dependent Schrödinger equation in a three dimensional system reads
For a one dimensional system it becomes just
As in the previous note, although we shall focus for the most part of this course on one dimensional systems, we shall carry through the developments in this note for the more general case of three dimensional systems which we will need when we study the hydrogen atom. To recover the one dimensional results, you need only remove the vector symbol ``'' and replace with in all of the equations below.
The method of the separation of variables is most often applied in the case of linear partial differential equations. We would like to emphasize at this point that the TDSE is linear, which means that the sum of any two solutions and to the equation gives a third valid solution . The student may verify this easily by direct substitution of into (1).
Note that in the equations below we have written the wave function, as with an upper case letter . We do this because momentarily we will separate the time and spatial dependencies of these equations and derive a new equation, the TISE, describing a time-independent wavefunction which we will denote with a lower case .