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Orthogonality of the eigenstates (Kronecker -function)

A useful property of the energy eigenstates is that they are orthogonal, the inner product between the pure states associated with two different energies is always zero, . Again the proof we give is completely general and is valid for any Hermitian operator.

If we agree to normalize our eigenstates properly so that we then may write compactly

where is the Kronecker -function, which is defined as

With this understood, the determination of the constants in the general expansion is now simple. To extract , we just take the inner product of with ,

With the we now may compute the probabilities of measuring the value in an experiment, . We may also use them to give an explicit form for the expansion of an arbitrary state in terms of the pure energy states ,

 



Prof. Tomas Alberto Arias
Thu Oct 12 16:07:59 EDT 1995