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Proof

With the variational principle and the multiple particle Schrödinger equation in hand, the mathematics of the proof of the virial theorem is straight forward. Our proof will be based on the observation from the variational principle that if we ``dilate'' one of the eigenstates taking then is stationary about the value () because here is just the eigenstate . To prove the virial theorem we now evaluate and set .

First, we evaluate the denominator of ,

 

Next we break the numerator into potential and kinetic parts,

The potential part gives,

 

We now finish with the kinetic energy part which is a bit more difficult because of the differential form of the kinetic energy operator.

 

Putting (26-28) together we have,

As discussed above, this must be stationary about ,

From this follows directly the general virial theorem for systems with homogeneous potential interactions ,



Prof. Tomas Alberto Arias
Thu Oct 12 16:07:59 EDT 1995