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Virial Theorem

Aside from its value in computer calculations, the variational principle is a very powerful theoretical tool. It allows us to prove an extremely general result, the Virial theorem, regarding the averages of the various terms in the energies for systems in pure energy states. In its most general form, the Virial theorem is true even for systems containing of many particles such as macroscopic objects.

The virial theorem states that if the potential energy function of a system of N particles is a homogeneous function of order v of the coordinates,

then for each and every pure state n of the total energy operator of energy the average kinetic energy and average potential energy of the system must obey

Examples we have see so far of this are the simple harmonic oscillator , the Hydrogen atom , and the bouncing ball . We have also touched on a multiple particle system which fits into this framework as well, the multiple electron atom. In fact, any system composed of electrons and nuclei, such as yourself, satisfies the conditions of the virial theorem. By far the most important force in systems composed of electrons and nuclei is the electrostatic force. In the case of a single atom, if is the position of the nucleus of charge Z and are the positions of the Z electrons, then we have N=Z+1 particles and In this case and cases with more than one nuclei, V is still a homogeneous function of order v=-1.

In all of these cases, the virial theorem allows us to make exact quantum mechanical statements about the pure energy states of systems,





Prof. Tomas Alberto Arias
Thu Oct 12 16:07:59 EDT 1995