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Preview of multiple particle systems

The formal part of this course deals almost exclusively with systems of one particle. While we have not yet discussed all the the physics of multiple particle systems, the general considerations we have laid out so far are sufficient for us to formulate and give a valid proof the virial theorem in the general case of more than one particle.

Within our framework, a systems of N particles is described by the coordinates of the particles in the system . Measurements of the positions of the particles in the system will lead to a distribution of results, where some probability function describes the probability of finding a particle in the small volume around and another particle in the volume about and so forth for all of N particles in the system. For a given quantum state of the system, this probability is given by the square of a quantum probability amplitude . The wavefunction of the pure state of energy will be an eigenstate of the Hamiltonian (total energy) operator,

 

where the Hamiltonian is the sum of the total kinetic and potential energy operators,

There is only one other fact about multiple particle systems, the Pauli Exclusion Principle, which puts additional constraints on the beyond those imposed by the Time Independent Schrödinger Equation (25). We will discuss this principle in a later note. All that we will need for now to demonstrate the virial theorem is the knowledge that satisfies condition (25).



Prof. Tomas Alberto Arias
Thu Oct 12 16:07:59 EDT 1995